Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

中国省域尺度17部门资本存量的时空特征分析     

刘丽  李宁  张正涛  冯介玲  陈曦  白扣  黄承芳 《地理科学进展》2019,38(4):546-555

随着灾害强度、频率以及承灾体暴露的增加,自然灾害造成的损失日益严重。资本存量作为承灾体的经济暴露指标之一,是灾害损失评估的前提和基础。针对目前中国缺乏省域尺度长时间序列的经济部门分类的资本存量数据基础,论文通过永续盘存法,建立了2003—2015年中国大陆31省17部门的资本存量数据库,并分析其时空特征。结果显示：① 全国总资本存量与灾害直接损失的年际变化均呈增加趋势。省域尺度上,通过相关性分析显示,在99%置信度水平上,两者呈显著正相关(r=0.3)。② 时间上,各省17部门资本存量基本也呈增加趋势,但增速不同。在各部门增速最快的省份中,黑龙江省的居民服务、修理和其他服务业增速最快,增长约454.3倍;其次是青海省的租赁和商务服务业(398.3倍)、江苏省的金融业(295.1倍)、安徽省的科学研究和技术服务业(125.1倍)等。③ 空间上,2015年各省17部门资本存量最多的前4个部门分别是房地产业,工业,交通运输、仓储和邮政业,水利、环境和公共设施管理业,占比均在60%以上;且这4个部门资本存量暴露最多的省份是江苏省和广东省。该结果有助于从时空角度了解各省各部门资本存量暴露情况,为各省灾害风险管理者的防灾减灾工作提供重要的参考价值。  相似文献   

The Roche Limit     

I. P. Williams 《Celestial Mechanics and Dynamical Astronomy》2003,87(1-2):13-25

The role of tides in deforming and possibly disrupting a secondary body orbiting about a primary body has been known for a considerable time. This was first inspired by the observations of ocean tides on Earth and then seen as playing an important role in the formation and evolution of the Earth–Moon system. Finally, in the beginning of the 20th century it was generally thought to have a significant role in the formation of the solar system through the tidal disruption of the Sun. Here, an overview of the historical developments of the ideas concerned with tidal disruption of a secondary body that can lead to mass loss is given. Some discussion of possible extensions to consider more realistic situations where the secondary body may not be moving on a circular orbit and may not rotate so as to maintain the phase-on configuration to the primary body is also given.  相似文献   

板翅式换热器综合性能优化的设计方法     

高俊忠  陈维汉 《广东海洋大学学报》2003,23(6):45-49

应用给定换热器结构材料而使换热量最大的两侧换热表面的最佳匹配准则和使可用能损失率最小的最佳运行参数准则。利用两个准则间的关系 ,采用迭代的方式完成换热器的优化设计 ,使换热器的设计达到材料省、换热效果好及运行费用低的目的 ,且能在设计阶段实现。  相似文献   

柴达木盆地东北缘古元古代变质镁铁—超镁铁质岩的地质特征及成因探讨     

王毅志  梁超云 《青海国土经略》2001,(Z1)

1:5万区域地质调查工作中,在柴达木陆块北缘首次发现古元古代变质镁铁—超镁铁质岩,获得成岩年龄为1952±15Ma,其岩石化学、地球化学特征反映出岩浆来源于亏损地幔,反映出该地区克拉通在古元古代(19亿年)发生了一次强烈的裂解(洋)事件,对于研究柴达木盆地北缘元古代结晶基底地质构造演化及进一步探讨柴达木盆地的起源及构造演化过程提供了重要地质线索。  相似文献   

Wolf-Rayet stars     

K. A. van der Hucht 《Astronomy and Astrophysics Review》1992,4(2):123-159

Summary Recent literature on Population I Wolf-Rayet star research extending from the Milky Way to blue compact dwarf galaxies is reviewed, broken down into inventory, basic parameters and galactic distribution, atmospheres, binaries, intrinsic variability, mass loss, enrichment and evolution. Also the incidence of Wolf-Rayet stars with variable non-thermal radio emission, excess X-ray fluxes, and episodic/periodic IR excesses is reviewed. These phenomena appear to be associated with wind-wind interaction in wide long-period WR+OB binaries and with wind-compact object interaction in WR+c binaries, with orbit sizes of the order of magnitude of the WR radio photosphere sizes or larger.  相似文献   

Observations of hydrogen deficient binary Upsilon sagittarii     

N. Kameswara Rao  V. R. Venugopal 《Journal of Astrophysics and Astronomy》1985,6(2):101-112

The absolute magnitudeM _v of the hydrogen deficient binary υ Sgr has been estimated as -4.8 ± 1.0 from the distribution of the interstellar reddening, polarization and interstellar lines of the surrounding stars. From the ANS observations obtained at the time of the secondary eclipse, it appears that the hotter secondary is surrounded by a disc with colours of a B8-B9 star. The λ 1550 CIv absorption line arising in the stellar wind does not show any change in strength during the secondary minimum. The upper limit to the mass-loss rate from the high temperature wind is estimated as ≤ 5 × 10^-7 M⊙ yr^-1 from the 2 cm and 6 cm radio observations. Based on observations obtained with the Astronomical Netherlands Satellite and VLA. The National Radio Astronomy Observatory’s Very Large Array at Socorro, New Mexico is operated by Associated Universities Inc. under contract with the National Science Foundation.  相似文献   

Some integrable cases of the two-body problem with mass depending both on time and distance     

J. A. Docobo 《Astronomy Letters》2003,29(5):344-347

an extension of the Gylden-Meshcherskii problem when the mass depends both on time and distance between two bodies is considered. certain mass loss laws as well as the Meshcherskii position vector and time transformation are used to convert the problem into the cases with equations of motion arising from integrable potentials.  相似文献   

深水导管架下水扶正过程定量风险分析     

余建星  谭振东  田佳 《海洋工程》2007,25(1):9-14

运用QRA技术(定量风险评估)对导管架下水过程进行深入分析,提出风险概率评价模型和事故损失综合评估方法。首先辨识潜在的风险事件及相关风险因素,然后量化风险事件的模糊概率和损失程度,最后依据风险量化结果和ALARP(aslow as reasonably practically)原则对需要控制的风险事件给出控制措施。通过定量风险分析,达到及时查找并消除各方面事故隐患的目的。  相似文献   

Numerical prediction of performance of submerged breakwaters   总被引：1，自引：0，他引：1  

A. Chiranjeevi Rambabu  J.S. Mani 《Ocean Engineering》2005,32(10):88-1246

The results of a numerical model study on the transmission characteristics of a submerged breakwater are presented. Study aimed to determine the effect of depth of submergence, crest width, initial wave conditions and material properties on the transmission characteristics of the submerged breakwater. The results highlight the optimum crest width of the breakwater and optimum clear spacing between two breakwaters. A submerged permeable breakwater with d_s/d=0.5, p=0.3 and f=1.0, reduces the transmission coefficient by about 10% than the impermeable breakwater. The results indicates an optimum width ratio of B/d=0.75 for achieving minimum transmission. By restricting the effective width ratio of the series of breakwaters to 0.75, studies were conducted to determine the effect of clear spacing between breakwaters on transmission coefficient, suggesting an optimum clear spacing of w/b=2.00 to obtain K_t below 0.6.  相似文献